The arch nemesis battle thing in MoTU and POP was never really cut and dry in my eyes.
It didn't really ever make logical sense, it was just always default in my opinion.
He-Man vs Skeletor
Man-At-Arms Vs Beastman
Teela vs Evil-Lynn
Stratos vs Mer-Man
Ram Man vs Trap Jaw
Orko vs Tri-clops
reaching...
Man-E-Faces vs Two-Bad
Mossman vs Stinkor
Roboto vs Whiplash
Cyclone vs Clawful
????? I don't know
I know these battles make little to no sense but these where the main good guys vs bad guys, everybody else never made enough appearances in the show to have an arch nemesis. Maybe Fisto vs Jitsu but only because they had the same action feature.
POP wise, I guess
She-Ra vs Hordak
Glimmer vs Mantenna
Bow vs Leech
Angella vs Catra
Castaspella vs Shadow Weaver
Frosta vs Grizzlor
Madame Razz, Broom and Kowl vs Scorpia
????? there really isn't a rhyme or reason laid out for you like in some other mythos and universes.



Got Fur 
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